Publications

2011

• All-printed infrared sensor based on multiwalled carbon nanotubes
  
  • Gohier Aurelien
  • Dhar Anirban
  • Gorintin Louis
  • Bondavalli Paolo
  • Bonnassieux Yvan
  • Cojocaru Costel Sorin
  Applied Physics Letters, American Institute of Physics, 2011, 98, pp.063103. This contribution deals with all-printed infrared sensors fabricated using multiwalled carbon nanotubes deposited on a flexible polyimide substrate. A high responsivity of up to 1.2 kV/W is achieved at room temperature in ambient air. We evidence a strong dependence of the device transduction mechanism on the surrounding atmosphere, which can be attributed to bolometric effect interference with water molecule desorption upon irradiation. (10.1063/1.3552686)
  DOI : 10.1063/1.3552686
• Real-time in situ Mueller matrix ellipsometry of GaSb nanopillars: observation of anisotropic local alignment
  
  • Nerbo Ingar Stian
  • Le Roy Sébastien
  • Foldyna Martin
  • Sondergard Elin
  • Kildemo Morten
  Optics Express, Optical Society of America - OSA Publishing, 2011, 19 (13), pp.12551-12561. The formation of GaSb nanopillars by low energy ion sputtering is studied in real-time by spectroscopic Mueller matrix ellipsometry, from the initial formation in the smooth substrate until nanopillars with a height of 200 - 300 nm are formed. As the nanopillar height increased above 100 nm, coupling between orthogonal polarization modes was observed. Ex situ angle resolved Mueller polarimetry measurements revealed a 180 degrees azimuth rotation symmetry in the off-diagonal Mueller elements, which can be explained by a biaxial material with different dielectric functions epsilon(x) and epsilon(y) in a plane parallel to the substrate. This polarization coupling can be caused by a tendency for local direction dependent alignment of the pillars, and such a tendency is confirmed by scanning electron microscopy. Such observations have not been made for GaSb nanopillars shorter than 100 nm, which have optical properties that can be modeled as a uniaxial effective medium (10.1364/OE.19.012551)
  DOI : 10.1364/OE.19.012551
• On the mechanisms of precipitation of graphene on nickel thin films
  
  • Baraton L.
  • He Z. B.
  • Lee C. S.
  • Cojocaru C.S.
  • Châtelet Marc
  • Maurice J.-L.
  • Lee Y.H.
  • Pribat D.
  EPL - Europhysics Letters, European Physical Society / EDP Sciences / Società Italiana di Fisica / IOP Publishing, 2011, 96, pp.46003. Growth on transition metal substrates is becoming a method of choice to prepare large-area graphene foils. In the case of nickel, where carbon has a significant solubility, such a growth process includes at least two elementary steps: (1) carbon dissolution into the metal, and (2) graphene precipitation at the surface. Here, we dissolve calibrated amounts of carbon in nickel films, using carbon ion implantation, and annealing at 725 °C or 900 °C. We then use transmission electron microscopy to analyse the precipitation process in detail: the latter appears to imply carbon diffusion over large distances and at least two distinct microscopic mechanisms. (10.1209/0295-5075/96/46003)
  DOI : 10.1209/0295-5075/96/46003
• Vertically oriented nickel nanorod/carbon nanofiber core/shell structures synthesized by plasma-enhanced chemical vapor deposition
  
  • He Zanbing
  • Lee Chang Seok
  • Maurice Jean Luc
  • Pribat Didier
  • Haghi-Ashtiani Paul
  • Cojocaru Costel Sorin
  Carbon, Elsevier, 2011, 49 (14), pp.4710-4718. Plasma-enhanced chemical vapor deposition, without a nickel-containing gaseous precur- sor, was used to synthesize continuous nickel (Ni) nanorods inside the hollow cavity of car- bon nanofibers (CNFs), thus forming vertically aligned Ni/CNF core/shell structures. Scanning and transmission electron microscopic images indicate that the elongated Ni nanorods originate from the catalyst particles at the tips of the CNFs and that their forma- tion is due to the effect of extrusion induced by the compressive force of the graphene lay- ers during growth. Different from previous work, each vertically-aligned core/shell structure reported is totally isolated from its neighbors. Continuous Ni nanorods are found to separate into smaller ones with increasing growth time, which was ascribed to (i) the limited amount of Ni available in the tip of the CNF, (ii) the polycrystalline nature of the Ni nanorods and (iii) the combined effects of the compressive stresses on the side of the Ni nanorods and of the tensile stress along their axis. (10.1016/j.carbon.2011.06.075)
  DOI : 10.1016/j.carbon.2011.06.075
• High-quality Single-walled carbon nanotubes synthesis by hot filament CVD on Ru nanoparticule catalyst
  
  • Bouanis Fatima Zara
  • Baraton Laurent
  • Huc Vincent
  • Pribat Didier
  • Cojocaru Costel Sorin
  Thin Solid Films, Elsevier, 2011, 519 (14), pp.4594-4597. We investigated the single-walled carbon nanotubes (SWCNTs) growth on Ru nanoparticle catalyst via hot filament assisted chemical vapor deposition (HFCVD) with two independent W filaments for the carbon precursor (methane) and the hydrogen dissociation respectively. The Ru nanoparticles were obtained following a two-step strategy. At first the growth substrate is functionalized by silanisation, then a self assembly of a ruthenium porphyrin complex monolayer on pyridine-functionalized metal oxide substrates. We have studied the impact of the filaments power and we optimized the SWCNTs growth temperature. The as grown SWCNTs were characterized by scanning electron microscopy (SEM), atomic force microscopy (AFM) and Raman spectroscopy. It was found that the quality, density and the diameter of SWCNTs depends on the filament and growth temperature. Results of this study can be used to improve the understanding of the growth of SWCNTs by HFCVD. (10.1016/j.tsf.2011.01.326)
  DOI : 10.1016/j.tsf.2011.01.326
• Analysis of textured films and periodic Grating Structures with Mueller Matrices: A new Challenge in Instrumentation with the generation of angle-resolved SE polarimeters
  
  • Ferrieu F.
  • Novikova Tatiana
  • Fallet Clément
  • Ben Hatit Sami
  • Vannuffel Cyril
  • de Martino Antonello
  Thin Solid Films, Elsevier, 2011, 519, pp.2608.
• Field emission measure of the time response of individual semiconducting nanowires to laser excitation
  
  • Choueib May
  • Ayari Anthony
  • Poncharal Philippe
  • Journet Catherine
  • Cojocaru Costel Sorin
  • Martel Richard
  • Purcell Steven T
  Applied Physics Letters, American Institute of Physics, 2011, 99, pp.072115. A simple technique is explored to determine the temporal photo-response, s, of individual semiconducting SiC and Si nanowires (NWs), with a high time resolution. Laser-assisted field emission (LAFE) from the NWs is first shown to be highly sensitive to continuous laser illumination. Pulsed illumination is then combined with measurements of the total energy distributions to determine s which were rather large, 4-200 ls. The time response scaled roughly with the square of the NWs length and could be attributed to laser-induced heating. LAFE is thus a new tool for quantifying rapid thermo-optical effects in such nano-objects. (10.1063/1.3627168)
  DOI : 10.1063/1.3627168
• Mueller polarimetry as a tool for evaluation of diffraction grating profile asymmetry
  
  • Novikova Tatiana
  • Bulkin Pavel
  • Popov V.
  • Haj Ibrahim Bicher
  • de Martino Antonello
  Journal of Vacuum Science and Technology, American Vacuum Society (AVS), 2011, 29 (5), pp.051804.
• Surface chemical modifications and surface reactivity of nanodiamonds hydrogenated by CVD plasma
  
  • Arnault Jean-Charles
  • Petit Tristan
  • Girard Hugues
  • Chavanne Anthony
  • Gesset Céline
  • Sennour Mohamed
  • Chaigneau Marc
  Physical Chemistry Chemical Physics, Royal Society of Chemistry, 2011, 13, pp.11481-11487. The present study focuses on the interaction of hydrogen microwave CVD plasma with nanodiamonds (NDs). Hydrogen treated NDs (H-NDs) were characterized using electron spectroscopies (XPS, AES) without air exposure. A surface temperature higher than 700 °C is needed to remove the oxygen present on raw NDs. The kinetics of oxygen removal were investigated. Moreover, UHV annealings of H-NDs after ageing in ambient air clearly underline that 75% of the oxygen is related to physisorbed species. Finally, H-NDs were efficiently grafted using photochemical reaction with alkenes and a spontaneous coupling of aryldiazonium salts. These results confirm similar electronic surface properties between bulk and nano diamond materials. (10.1039/C1CP20109C)
  DOI : 10.1039/C1CP20109C
• Radiation damage induced at the surface of titanium by argon ions of a few MeV
  
  • Do N.-L.
  • Bérerd N.
  • Moncoffre N.
  • Yang F.
  • Trocellier P.
  • Serruys Y.
  • Gorse-Pomonti D.
  Journal of Nuclear Materials, Elsevier, 2011, 419, pp.168-176. Oxide films thermally grown on titanium in a weakly oxidizing environment (5 × 10−3 Pa of dry air) under irradiation with 2, 4 and 9 MeV argon have been studied. The AFM study reveals a cratering effect of 2, 4 and 9 MeV argon and a significant surface roughening effect of 2 MeV argon, both effects being largely unexpected in this energy range. The XPS analysis shows that the TiO2 stoichiometry of the superficial oxide film is fairly well maintained under argon irradiation. The Spectroscopic Ellipsometry analysis reveals an oxide film thickness multiplied by a factor of three under irradiation with 2 MeV argon by comparison with 9 MeV argon, the irradiation effect on oxide growth remaining very limited for 4 or 9 MeV argon. The possible role of the electronic but most certainly of the nuclear energy losses on the surface damage mechanism are discussed. It is suggested that the oxidizing environment is necessary to freeze the instantaneous surface damage and permits the post-mortem observation. (10.1016/j.jnucmat.2011.07.012)
  DOI : 10.1016/j.jnucmat.2011.07.012